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Oil Spills and the Marine Environment
company said, "The best thing you can do is uncork another
bottle of whiskey!"
TREATING
AGENTS
A number of materials have been used to remove or reduce oil
slicks. Treating agents have been used to deal with accidents and
field and laboratory experiments have been done to assess their
usefulness and to develop the technology to use them. The types of
agents which have been used to date are:
-
Dispersants—chemicals forming oil-in-water
suspensions;
-
Sinking
agents—materials that mix with the oil and create a mixture
dense enough to sink;
-
Burning
agents—material put on the slick to assist ignition or
enhance combustion of spilled oil;
-
Biodegradants—substances that promote
oxidation of oil by microbial action;
-
Gelling
agents—chemicals that form semi-solid oil agglomerates to
facilitate removal;
-
Herding
agents—chemicals that concentrate the spilled oil in a small
area;
-
Sorbents—materials that absorb or adsorb oil
to form a floating mass for later collection and
removal.
Dispersants
Dispersants
are chemical compounds that act to enhance the surface spreading of
oil slicks and to emulsify the oil into the water beneath it. These
effects increase the surface area of the slick so that more of it
is susceptible to biodegradation. When emulsification (breaking the
oil into very small droplets that become mixed with the water)
occurs, the slick disperses vertically as well as horizontally.
Toxicity of dispersed slicks is a major problem () and is due both
to the effect of the dispersant and to the increased oil surface to
which marine organisms are exposed. Considerable research has been
devoted to the problem of dispersant toxicity.
The federal Council on Environmental Quality (CEQ) developed a
National Oil and Hazardous Materials Pollution Contingency
Plan in August 1971 (). This plan, enforced by the U.S. Coast
Guard and the Environmental Protection Agency, requires that
dispersants not be used:
-
On any
distillate fuel oil.
-
On any spill
of less than 200 barrels.
-
On any
shoreline.
-
In waters
less than 500 feet deep.
-
In waters
containing major fish populations, or breeding or passage areas
for